REACTIONS BETWEEN W2I4(CO)8 AND PHOSPHINES UNDER FORCING CONDITIONS - ATTEMPTED DECARBONYLATION TO TUNGSTEN(II) DIMERS WITH QUADRUPLE METAL METAL BOND - X-RAY MOLECULAR-STRUCTURE OF WI2(CO)(DPPM)2

被引：6

作者：

COTTON, FA ^{[1
]}

FALVELLO, LR ^{[1
]}

POLI, R ^{[1
]}

机构：

[1] TEXAS A&M UNIV,MOLEC STRUCT & BONDING LAB,COLLEGE STN,TX 77843

来源：

POLYHEDRON | 1987年 / 6卷 / 05期

关键词：

D O I：

10.1016/S0277-5387(00)80967-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：1135 / 1142

页数：8

共 16 条

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[4]

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[5] DECARBONYLATION OF MOLYBDENUM(II) CARBONYL-COMPLEXES - A NEW ROUTE TO QUADRUPLY BONDED MOLYBDENUM(II) DIMERS [J].

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (18) :5628-5629

[6] THERMAL-REACTION OF MO2I4(CO)8 WITH PME2PH, PET2PH, AND PYRIDINE - FORMATION OF METAL METAL QUADRUPLE BONDS VS DISPROPORTIONATION - X-RAY CRYSTAL-STRUCTURES OF MOI3(PME2PH)2(POME2PH) AND [PHET2PH][MOI4(PET2PH)2] [J].

COTTON, FA ;

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INORGANIC CHEMISTRY, 1986, 25 (20) :3624-3629

[7] PRODUCTS OF THE REACTION BETWEEN MO2I4(CO)8 AND BIS(DIMETHYLPHOSPHINO)METHANE (DMPM) - X-RAY CRYSTAL-STRUCTURE OF MOI2(CO)(DMPM)2.C7H8 [J].

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INORGANIC CHEMISTRY, 1986, 25 (20) :3703-3705

[8] MOLECULAR AND ELECTRONIC-STRUCTURES OF 2 QUADRUPLY BONDED DITUNGSTEN COMPOUNDS AND A DIMOLYBDENUM HOMOLOG [J].

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[9] SYNTHESIS AND MOLECULAR-STRUCTURE OF MO2I4(BIS(DIPHENYPHOSPHINO)METHANE)2.2C7H8 [J].

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[10] REACTIONS OF MO2CL4(PR3)4 AND W2CL4(PR3)4 WITH CARBON-MONOXIDE [J].

COTTON, FA ;

DARENSBOURG, DJ ;

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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 217 (01) :C14-C16

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