STRUCTURES AND MAGNETIC PROPERTIES OF SOME METAL (I) CHROMIUM (3) SULFIDES AND SELENIDES

被引:168
作者
BONGERS, PF
VANBRUGG.CF
KOOPSTRA, J
OMLOO, WPF
WIEGERS, GA
JELLINEK, F
机构
[1] Philips Research Laboratories, Eindhoven
关键词
D O I
10.1016/0022-3697(68)90234-5
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structures of M1CrX2(M = Na, Cu, Ag; X = S, Se) have been determined. The structures of CuCrX2 and AgCrX2 differ from those reported in literature. The susceptibility has been measured between 4 and 800°K. The compounds are antiferromagnetic with Néel temperatures between 19 and 50°K. Ferromagnetic interactions in the chromium layers occur in NaCrS2, NaCrSe2 and AgCrSe2. NaCrS2 probably has a helical spin structure. © 1968.
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页码:977 / &
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