A VIBRATIONAL ASSIGNMENT OF ACENAPHTHENE

被引：19

作者：

BREE, A

KYDD, RA

MISRA, TN

机构：

[1] Chemistry Department, University of British Columbia

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1969年 / A 25卷 / 11期

关键词：

D O I：

10.1016/0584-8539(69)80210-2

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The Raman spectra of a single crystal of acenaphthene have been recorded in all possible orientations and this information has been supplemented by the measurement of depolarization ratios of the Raman lines in solution spectra. The polarized infrared spectra of an ac crystal section have been measured in the region below 600 cm-1 in order to complete the vibrational analysis in the low-frequency region. The frequencies of the normal modes were calculated using a simplified valence force field transferred from naphthalene and cyclopentane. These calculated values were compared with an experimental assignment that was based on the assumption that deviations from an oriented-gas model were small. © 1969.

引用

页码：1815 / &

共 19 条

[1] VIBRATIONAL ASSIGNMENT OF ANTHRACENE-D10 FROM FLUORESCENCE AND ABSORPTION SPECTRA [J].