OXIDATIVE COUPLING OF 4,5,6-TRICHLOROGUAIACOL WITH IRON(III) HEXACYANOFERRATE(III)

被引：3

作者：

ARNOLDSSON, KC

WACHTMEISTER, CA

机构：

[1] Environmental Chemistry, Wallenberg Laboratory, Stockholm University

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 04期

关键词：

D O I：

10.1016/S0040-4039(00)79492-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iron(III) hexacyanoferrate(III) is shown to be a useful reagent in oxidative coupling of 4,5,6-trichloroguaiacol (4,5,6-TCG). Dimerisation proceeds via oxidative demethylation and loss of chloride to give an ortho-quinonoid dimer in high yield. The proposed structure 1 is based largely on mass-spectra of methyl derivatives of the corresponding diol.

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页码：543 / 546

页数：4

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