SIMPLE PREPARATION OF BIS-ARENE-RUTHENIUM CATIONIC COMPLEXES, INCLUDING THOSE CONTAINING DIFFERENT ARENES

被引：117

作者：

BENNETT, MA

MATHESON, TW

机构：

[1] Research School of Chemistry, The Australian National University, A.C.T., 2600, P.O. Box 4, Canberra

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 175卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)82301-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis-η6-arene-ruthenium(II) salts of general formula [Ru(arene1)(arene2)]Y2 (arene1 = benzene, mesitylene or hexamethylbenzene, arene2 = a wide range of aromatic compounds and Y = BF4 or PF6) can be prepared in moderate to high yields by treatment of [RuCl2(η6-arene1)]2 in acetone successively with AgBF4 or AgPF6, acid (CF3CO2H, HBF4 or HPF6) and arene2. © 1979.

引用

页码：87 / 93

页数：7

共 25 条

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