PYROLYTIC FRAGMENTATION AND REARRANGEMENT OF 1-METHOXYCYCLOPROPYLAMINES

被引：3

作者：

DEKIMPE, N

DEBUCK, K

BOOTEN, K

机构：

[1] Laboratory of Organic Chemistry, Faculty of Agricultural Sciences, State University of Gent, B-9000 Gent

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 03期

关键词：

D O I：

10.1016/S0040-4039(00)74140-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Alkyl 2,2-dialkyl-1-methoxycyclopropylamines undergo a pyrolytic fragmentation into alkylisocyanides, methanol, 1,1-dialkylethylenes and novel alpha,beta-unsaturated ketimines. Synthetic methods were developed for the generation of the latter 1-aza-1,3-dienes.

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页码：393 / 396

页数：4

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