COMPLEXES OF SILVER(I) WITH BIS(DIALKYLDITHIOCARBAMATO)PLATINUM(II) AS LIGAND - SYNTHESIS AND STRUCTURES OF [PT3(S2CNPRI2)6AG2[(BF4)2 AND [PT3(S2CNBUN2)6AG2](CLO4)2

被引：14

作者：

EBIHARA, M

TOKORO, K

IMAEDA, K

SAKURAI, K

MASUDA, H

KAWAMURA, T

机构：

[1] GIFU UNIV,FAC ENGN,DEPT CHEM,GIFU 50111,JAPAN

[2] NAGOYA INST TECHNOL,DEPT APPL CHEM,SHOWA KU,NAGOYA,AICHI 466,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 21期

关键词：

D O I：

10.1039/c39920001591

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(dialkyldithiocarbamato)platinum(II) complexes with Pr(i) or Bu(n) substituents on the dithiocarbamato ligands and Ag(I) salts gave the complexes in the title with 1J(Pt-195-Ag-107, Ag-109) of ca. 200 Hz indicating a Pt-Ag bonding interaction; their X-ray structures showed that they consist of two Ag atoms separated by ca. 3.0 angstrom surrounded by three molecules of the starting Pt complex.

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页码：1591 / 1592

页数：2

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