NITROALKANES IN C-C BOND FORMING REACTIONS - A CRYSTAL-STRUCTURE OF A COMPLEX OF A GUANIDINE CATALYST AND A NITROALKANE SUBSTRATE

被引：47

作者：

VANAKEN, E

WYNBERG, H

VANBOLHUIS, F

机构：

[1] DEPT ORGAN CHEM,NIJENBORGH 16,9747 AG GRONINGEN,NETHERLANDS

[2] DEPT CRYSTALLOG,DEPT CRYSTALLOG,9747 AG GRONINGEN,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 08期

关键词：

D O I：

10.1039/c39920000629

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD), a good catalyst for nitroalkanes in C-C bond forming reactions, forms a 1 : 1 complex 3 with alpha-nitrotoluene as a substrate, as shown by a crystal structure determination.

引用

页码：629 / 630

页数：2

共 21 条

[1]

ANDRUSZKIEWICZR, 1989, SYNTHESIS-STUTTGART, P953

[2]

[Anonymous], ANGEW CHEM

[3]

Barrett A. G. M., 1988, TETRAHEDRON LETT, V29, P5733

[4] ASYMMETRIC INDUCTION IN BASE-CATALYZED MICHAEL ADDITION OF NITROMETHANE TO CHALCONE [J].

COLONNA, S ;

HIEMSTRA, H ;

WYNBERG, H .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (06) :238-239

[5] CHIRAL RECOGNITION OF AROMATIC CARBOXYLATE ANIONS BY AN OPTICALLY-ACTIVE ABIOTIC RECEPTOR CONTAINING A RIGID GUANIDINIUM BINDING SUBUNIT [J].

ECHAVARREN, A ;

GALAN, A ;

LEHN, JM ;

DEMENDOZA, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (13) :4994-4995

[6] ANION-RECEPTOR MOLECULES - SYNTHESIS OF A CHIRAL AND FUNCTIONALIZED BINDING SUBUNIT, A BICYCLIC GUANIDINIUM GROUP DERIVED FROM L-ASPARAGINE OR D-ASPARAGINE [J].

ECHAVARREN, A ;

GALAN, A ;

DEMENDOZA, J ;

SALMERON, A ;

LEHN, JM .

HELVETICA CHIMICA ACTA, 1988, 71 (04) :685-693

[7] ENANTIODIFFERENTIATION OF CARBOXYLATES BY CHIRAL BUILDING-BLOCKS FOR ABIOTIC ANION RECEPTORS [J].

GLEICH, A ;

SCHMIDTCHEN, FP ;

MIKULCIK, P ;

MULLER, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (01) :55-58

[8]

HELDER R, 1975, TETRAHEDRON LETT, P4057

[9] THE CHEMISTRY OF ALIPHATIC AND ALICYCLIC NITRO COMPOUNDS .8. THE REDUCTION OF OPTICALLY ACTIVE 2-NITROOCTANE AND ALPHA-PHENYLNITROETHANE [J].

KORNBLUM, N ;

FISHBEIN, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (23) :6266-6269

[10] ABIOTIC ANION RECEPTOR FUNCTIONS - A FACILE AND DEPENDABLE ACCESS TO CHIRAL GUANIDINIUM ANCHOR GROUPS [J].

KURZMEIER, H ;

SCHMIDTCHEN, FP .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (12) :3749-3755

← 1 2 3 →