TIME-RESOLVED OBSERVATION OF MOLECULAR PSEUDOROTATION IN NA3

被引：21

作者：

KOBE, K ^{[1
]}

KUHLING, H ^{[1
]}

RUTZ, S ^{[1
]}

SCHREIBER, E ^{[1
]}

WOLF, JP ^{[1
]}

WOSTE, L ^{[1
]}

BROYER, M ^{[1
]}

DUGOURD, P ^{[1
]}

机构：

[1] UNIV LYON 1,CNRS,SPECTROMETRIE ION & MOLEC LAB 171,F-69622 VILLEURBANNE,FRANCE

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 213卷 / 5-6期

关键词：

D O I：

10.1016/0009-2614(93)89159-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The temporal behaviour of the pseudorotating B state of Na3 was investigated in a two-photon-ionization (TPI) experiment, employing picosecond laser pulses and a variable delay between the excitation and ionization step. The results exhibit the pseudorotational motion as a temporal sequence. The detailed analysis of the vibronic function time evolution affirms a pseudo-Jahn-Teller (PJT) model for the interpretation of the B state spectroscopic data.

引用

页码：554 / 558

页数：5

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