FORMATION OF ORGANOCOBALT PORPHYRIN COMPLEXES BY REACTIONS OF COBALT(II) PORPHYRINS WITH AZOISOBUTYRONITRILE AND ORGANIC SUBSTRATES

被引：27

作者：

GRIDNEV, AA

ITTEL, SD

FRYD, M

WAYLAND, BB

机构：

[1] UNIV PENN,DEPT CHEM,PHILADELPHIA,PA 19104

[2] DUPONT & CO,CENT RES & DEV,EXPTL STN,WILMINGTON,DE 19880

[3] DUPONT & CO,MARSHALL LAB,PHILADELPHIA,PA 19146

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 12期

关键词：

D O I：

10.1039/c39930001010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of a cobalt(II) porphyrin with azoisobutyronitrile (AIBN) at 333 K provides a convenient source of a transient cobalt hydride that reacts with alkenes and alkynes to form secondary alkyl and vinyl complexes, respectively or alternatively with organic halides and epoxides in the presence of donor molecules to form primary alkyl and beta-hydroxyalkyl complexes.

引用

页码：1010 / 1011

页数：2

共 7 条

[1] CATALYZED CHAIN TRANSFER TO MONOMER IN FREE-RADICAL POLYMERIZATION [J].