THE CONVERSION OF CARBOXYLIC-ACIDS TO AMIDES VIA TIN(II) REAGENTS

被引:36
作者
BURNELLCURTY, C [1 ]
ROSKAMP, EJ [1 ]
机构
[1] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208
关键词
D O I
10.1016/S0040-4039(00)73950-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Unsymmetrical tin(II) amides can be generated, in situ, by adding one equivalent of an amine to bis(bistrimethylsilylamino) tin, Sn[N(TMS)2]2. Treatment of carboxylic acids with these tin(II) reagents derived from alkyl or aryl amines results in smooth conversion to the corresponding N-alkyl or N-aryl amides.
引用
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页码:5193 / 5196
页数:4
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