SYNTHESIS, STRUCTURE, AND REACTIVITY OF AN IMIDOPHOSHORANE AND AN OXO(IMIDO)PHOSPHORANE R-P(=X)=NR (X=NH, O R=TBU(3)C(6)H(2)

被引：19

作者：

LARBIG, M ^{[1
]}

NIEGER, M ^{[1
]}

VONDERGONNA, V ^{[1
]}

RUBAN, AV ^{[1
]}

NIECKE, E ^{[1
]}

机构：

[1] UNIV BONN,INST ANORGAN CHEM,D-53121 BONN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 04期

关键词：

NITROGEN COMPOUNDS; PHOSPHORANES; PHOSPHORUS COMPOUNDS;

D O I：

10.1002/anie.199504601

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A high synthetic potential is promised by imido(imino)phosphorane 2 accessible by N2 elimination from the azidophosphane 1. In 2, as in the isoelectronic oxygen derivative 3, the phosphorus atom is in a trigonal‐planar environment. Ar = 2,4,6‐tBu3C6H2. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：460 / 462

页数：3

共 21 条

[1]

Niecke E., Gudat D., Multiple Bonds and Low Coordination in Phosphorus Chemistry, pp. 392-404, (1991)

[2]

Keim W., Appel R., Storeck A., Kruger C., Goddard R., Angew. Chem., 93, pp. 91-92, (1981)

[3]

Angew. Chem. Int. Ed. Engl., 20, (1981)

[4]

Fink G., Mohring V., Stud. Surf. Sci. Catal., 25, (1986)

[5]

Ruban A., Nieger M., Niecke E., Angewandte Chemie, 105, pp. 1544-1545, (1993)

[6]

Angew. Chem. Int. Ed. Engl., 32, (1993)

[7]

Markovskii L.N., Romanenko V.D., Ruban A.V., Drapailo A.B., (1984)

[8]

Lysek M.

[9]

Baceiredo A., Bertrand G., Majoral J.P., Sicard G., J. Am. Chem. Soc., 106, pp. 6088-6089, (1984)

[10]

Boske J., Niecke E., Ocando-Mavarez E., Majoral J.P., Bertrand G., Inorg. Chem., 25, pp. 2695-2698, (1986)

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