ACTIVITY OF LITHIUM IN LITHIUM AMALGAMS

被引：32

作者：

COGLEY, DR

BUTLER, JN

机构：

[1] Tyco Laboratories, Inc., Waltham

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1968年 / 72卷 / 03期

关键词：

D O I：

10.1021/j100849a040

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Activity coefficients of lithium in its amalgams have teen measured using the cell Li(s)|Li+, X-Li(Hg), where X- is Cl- or ClO4-, with anhydrous dimethyl sulfoxide as solvent. The activity coefficient (mole fraction scale, reference state infinite dilution) is given by the relation, log γLi = (14.6 ± 0.4) XLi, for XLi < 0.013 (saturation), and the solutions appear to be regular within experimental error. The standard potential difference between the solid lithium and lithium amalgam electrodes is 0.8438 ± 0.0002 V. A saturated amalgam at 25° contains 1.33 mole % lithium.

引用

页码：1017 / &

共 19 条

[1]

COGLEY DR, 1966, J ELECTROCHEM SOC, V113, P1074

[2]

DAVIES MO, AD609294

[3]

DAVIES MO, 1957, PHYSICAL CHEMICAL PR

[4]

DAVIES MO, NONR58100 CONTR

[5]

DAVIES MO, AD138849 2

[6] THE THERMODYNAMIC PROPERTIES OF DILUTE ALKALI METAL AMALGAMS [J].

FRIEDMAN, HL ;

SCHUG, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (16) :3881-3888

[7]

Hansen M., 1958, J ELECTROCHEM SOC, DOI DOI 10.1149/1.2428700

[8]

Hildebrand J. H., 1950, SOLUBILITY NONELECTR

[9] ANALYSIS AND DISTILLATION OF PROPYLENE CARBONATE [J].

JASINSKI, RJ ;

KIRKLAND, S .

ANALYTICAL CHEMISTRY, 1967, 39 (13) :1663-&

[10] The potential of the lithium electrode. [J].

Lewis, GN ;

Keyes, FG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1913, 35 :340-344

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