THE CHEMISTRY OF (R)-5-TRIMETHYLSILYL-2-CYCLOHEXENONES AND (S)-5-TRIMETHYLSILYL-2-CYCLOHEXENONES

被引:5
作者
ASAOKA, M
TAKEI, H
机构
[1] Department of Life Chemistry, Tokyo Institute of Technology
关键词
D O I
10.5059/yukigoseikyokaishi.48.216
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The preparation and the reaction of enantiomerically pure (R) – and (S)-5-trimethylsilyl-2-cyclohexenone are described. The enones can undergo diastereospecific alkylation or conjugate addition leading to the corresponding substituted cyclohexe (a) nones with a newly created tertiary or quaternary chiral center. The synthesis of some optically active natural products utilizing the enantiomerically pure enones are also described. © 1990, The Society of Synthetic Organic Chemistry, Japan. All rights reserved.
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页码:216 / 228
页数:13
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