4-PENTYNOIC AND 5-HEXYNOIC ACID FROM JONES OXIDATION OF 5-HEXYNOL

被引：9

作者：

JUST, G ^{[1
]}

LUTHE, C ^{[1
]}

OH, H ^{[1
]}

MONTGOMERY, J ^{[1
]}

机构：

[1] MCGILL UNIV,MRC,BIOMED MASS SPECT UNIT,MONTREAL H3C 3G1,QUEBEC,CANADA

来源：

SYNTHETIC COMMUNICATIONS | 1979年 / 9卷 / 07期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1080/00397917908066707

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Recently, Holland and Gilman1 reported an improved procedure for the oxidation of alkynols to alkynoic acids* According to it the alkynol is added to a solution of Jones reagent* We had occasion to repeat the procedure on 5-hexynol several times, isolating “5-hexynoic acid (1) “, b.p. 108°/10 mm, in somewhat lower yield (55-60%) than described. © 1979, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：613 / 617

页数：5