RATE-CONSTANT AND PRODUCTS OF THE BRO + BRO REACTION AT 298-K

被引：16

作者：

LANCAR, IT ^{[1
]}

LAVERDET, G ^{[1
]}

LEBRAS, G ^{[1
]}

POULET, G ^{[1
]}

机构：

[1] CNRS,CTR RECH CHIM COMBUST & HAUTES TEMP,F-45071 ORLEANS 2,FRANCE

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1991年 / 23卷 / 01期

关键词：

D O I：

10.1002/kin.550230105

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The overall rate coefficient k of the self recombination of BrO radicals has been measured at 298 K with use of the discharge flow/mass spectrometry technique. The rate coefficient k2 for the reaction channel forming Br2 has been also determined. The results are: k = (3.2 +/- 0.5) x 10(-12) and k2 = (4.7 +/- 1.5) x 10(-13) (in cm3 molecule-1 s-1). These results are discussed with respect to previous literature data.

引用

页码：37 / 45

页数：9

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