MONITORING AND CONFIRMING PRIMARY ALKYLAMINES VIA A SIMPLE DERIVATIZATION PROCEDURE

被引:14
作者
GAIND, VS
CHAI, F
机构
[1] Occupational Health Laboratory, Ontario Ministry of Labour, Weston, Ont. M9P 3T1
关键词
Dithiocarbamate; Gas chromatography; Isothiocyanate; Primary alkylamine derivatisation;
D O I
10.1039/an9901500143
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Carbon disulphide reacts readily with primary alkylamines to yield dithiocarbamates. When injected into the heated injection port of a gas chromatograph, the dithiocarbamates yield the corresponding isothiocyanates. This reaction provides a simple and elegant derivatisation for quantifying, and also confirming the identity of, the primary alkylamines.
引用
收藏
页码:143 / 145
页数:3
相关论文
共 6 条
[1]   TOXICOLOGICAL DETECTION OF TRACES OF BIOLOGICALLY-ACTIVE AMINES(AMPHETAMINE, CATECHOLAMINES, HALLUCINOGENS) BY GAS-CHROMATOGRAPHY WITH MASS SPECIFIC DETECTION [J].
BRANDENBERGER, H ;
SCHNYDER, D .
FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1972, 261 (4-5) :297-+
[2]   REACTION OF CARBON DISULFIDE WITH PRIMARY AND SECONDARY ALIPHATIC AMINES AS AN ANALYTICAL TOOL [J].
CRITCHFIELD, FE ;
JOHNSON, JB .
ANALYTICAL CHEMISTRY, 1956, 28 (04) :430-436
[3]  
HOFMANN AW, 1868, BER, V1, P169
[4]   GAS-LIQUID CHROMATOGRAPHY AND MASS-SPECTROMETRY OF BIOGENIC-AMINES AND AMPHETAMINES AS THEIR ISOTHIOCYANATE DERIVATIVES [J].
NARASIMHACHARI, N ;
VOUROS, P .
ANALYTICAL BIOCHEMISTRY, 1972, 45 (01) :154-+
[5]  
1988, AM C GOVT IND HYGIEN
[6]  
NIOSH82100 PUBL