MONITORING AND CONFIRMING PRIMARY ALKYLAMINES VIA A SIMPLE DERIVATIZATION PROCEDURE

被引：14

作者：

GAIND, VS

CHAI, F

机构：

[1] Occupational Health Laboratory, Ontario Ministry of Labour, Weston, Ont. M9P 3T1

来源：

ANALYST | 1990年 / 115卷 / 02期

关键词：

Dithiocarbamate; Gas chromatography; Isothiocyanate; Primary alkylamine derivatisation;

D O I：

10.1039/an9901500143

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Carbon disulphide reacts readily with primary alkylamines to yield dithiocarbamates. When injected into the heated injection port of a gas chromatograph, the dithiocarbamates yield the corresponding isothiocyanates. This reaction provides a simple and elegant derivatisation for quantifying, and also confirming the identity of, the primary alkylamines.

引用

页码：143 / 145

页数：3

共 6 条

[1] TOXICOLOGICAL DETECTION OF TRACES OF BIOLOGICALLY-ACTIVE AMINES(AMPHETAMINE, CATECHOLAMINES, HALLUCINOGENS) BY GAS-CHROMATOGRAPHY WITH MASS SPECIFIC DETECTION [J].