C-H BOND-CLEAVAGE OF 8-QUINOLINECARBALDEHYDE BY SIGMA,ETA(3)-ALLYL RHODIUM(III) COMPLEXES

被引：6

作者：

JUN, CH ^{[1
]}

LIM, YG ^{[1
]}

机构：

[1] AGCY DEF DEV,YUSEONG 305600,SOUTH KOREA

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 19期

关键词：

D O I：

10.1016/0040-4039(95)00540-S

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Formation of sigma,eta(3)-allyl rhodium complexes from vinylcyclopropanes and Rh(I), its application to C-H bond cleavage of 8-quinolinecarbaldehyde, and generation of alkyl-substituted eta(3)-allyl rhodium complexes are demonstrated. Ligand-promoted reductive eliminations of alkyl-substituted eta(3)-allyl rhodium complexes with P(OMe)(3) produce beta,gamma-unsaturated ketones.

引用

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页码：3357 / 3360

页数：4

相关论文

共 21 条

[1] FURTHER-STUDIES ON METAL-PROMOTED VINYLCYCLOPROPANE TO CYCLOPENTENE REARRANGEMENTS - STRUCTURE AND THERMOLYSIS OF RHODIUM COMPLEXES OF EXO-6-VINYLBICYCLO[3.1.0]HEX-2-ENE AND THE CRYSTAL-STRUCTURE OF THE 1,6-8-ETA-4-5-ALLYLCYCLOPENT-2-ENYL(HEXAFLUOROACETYLACETONATO)RHODIUM(III) TETRAMER [J].

ALCOCK, NW ;

BROWN, JM ;

CONNEELY, JA ;

WILLIAMSON, DH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1979, (07) :962-971

[2] IRON CARBONYL-COMPLEXES FROM VINYLCYCLOPROPANE [J].

AUMANN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (08) :2631-2632

[3] SYNTHESIS AND REACTIVITY OF (ETA-5-C5H7)FE(PME3)3+O3SCF3- - C-C BOND FORMATION VIA NUCLEOPHILIC-ADDITION TO C2 OF AN ETA-5-PENTADIENYL LIGAND [J].

BLEEKE, JR ;

HAYS, MK .

ORGANOMETALLICS, 1987, 6 (06) :1367-1369

[4] PENTADIENYL METAL PHOSPHINE CHEMISTRY .20. REGIOSELECTIVE AND DIASTEREOSELECTIVE ADDITION OF ALKYL ANIONS TO ELECTRON-RICH (ETA-5-PENTADIENYL)IRON COMPLEXES [J].

BLEEKE, JR ;

WITTENBRINK, RJ ;

CLAYTON, TW ;

CHIANG, MY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (18) :6539-6545

[5] RING-OPENING HYDROFORMYLATION OF ALPHA-CYCLOPROPYLSTYRENE BY HMN(CO)5, AND STRUCTURE OF A NOVEL MN-2(CO)9(ETA-1-ALDEHYDE) COMPLEX [J].

BULLOCK, RM ;

RAPPOLI, BJ ;

SAMSEL, EG ;

RHEINGOLD, AL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (04) :261-263

[6] HYDROGEN-ATOM TRANSFER-REACTIONS OF TRANSITION-METAL HYDRIDES - UTILIZATION OF A RADICAL REARRANGEMENT IN THE DETERMINATION OF HYDROGEN-ATOM TRANSFER RATES [J].

BULLOCK, RM ;

SAMSEL, EG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (21) :6542-6544

[7] HYDROGEN-ATOM TRANSFER-REACTIONS OF TRANSITION-METAL HYDRIDES - KINETICS AND MECHANISM OF THE HYDROGENATION OF ALPHA-CYCLOPROPYLSTYRENE BY METAL-CARBONYL HYDRIDES [J].

BULLOCK, RM ;

SAMSEL, EG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (19) :6886-6898

[8] CONCERNING THE REACTION OF (ETA-5-1-METHOXYCARBONYLPENTADIENYL)(TRICARBONYL)IRON(+1) WITH MALONATE ANION - A STRUCTURAL CORRECTION [J].

DONALDSON, WA ;

RAMASWAMY, M .

TETRAHEDRON LETTERS, 1989, 30 (11) :1343-1344

[9] RING-OPENING AND RING-CLOSURE OF VINYLCYCLOPROPANES ON RH AND APPLICATION TO UNSTRAINED C-C BOND-CLEAVAGE [J].

JUN, CH ;

KANG, JB ;

LIM, YG .

TETRAHEDRON LETTERS, 1995, 36 (02) :277-280

[10]

JUN CH, 1991, B KOR CHEM SOC, V12, P251