TRIFLUOROACETYL CHLORIDE FOR CHARACTERIZATION OF ORGANIC FUNCTIONAL-GROUPS BY F-19 NUCLEAR MAGNETIC-RESONANCE SPECTROMETRY

被引：46

作者：

SLEEVI, P ^{[1
]}

GLASS, TE ^{[1
]}

DORN, HC ^{[1
]}

机构：

[1] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061

来源：

ANALYTICAL CHEMISTRY | 1979年 / 51卷 / 12期

关键词：

D O I：

10.1021/ac50048a009

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The potential utility of trifluoroacetyl chloride as an analytical 19F NMR reagent to characterize alcohols, phenols, thiols, and primary and secondary amines is reported. The 19F chemical shift and yield data for trifluoroacetyl derivatives of approximately 50 model compounds are presented. The importance of an added organic base (2,6-lutidine) in derivative preparation for phenols and primary and secondary amines is discussed. © 1979, American Chemical Society. All rights reserved.

引用

页码：1931 / 1934

页数：4

共 14 条

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