CARBOHYDRATE REACTIVITY IN HYDROGEN-FLUORIDE .10. HYDROGEN FLUORIDE-MEDIATED SYNTHESIS OF 1-THIOTREHALOSES INVOLVING REACTION OF D-GLUCOSE WITH HYDROGEN-SULFIDE

被引：26

作者：

DEFAYE, J ^{[1
]}

GADELLE, A ^{[1
]}

PEDERSEN, C ^{[1
]}

机构：

[1] TECH UNIV DENMARK,DK-2800 LYNGBY,DENMARK

来源：

CARBOHYDRATE RESEARCH | 1991年 / 217卷

关键词：

D O I：

10.1016/0008-6215(91)84116-V

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Hydrogen sulfide reacted with D-glucose in hydrogen fluoride solution to yield preponderantly alpha,alpha-1-thiotrehalose, beta-beta-1-thiotrehalose, and the alpha,beta anomer. Conditions were found under which the thiotrehaloses were obtained in the respective proportions of 8:5:5.

引用

页码：51 / 58

页数：8

共 12 条

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