EMISSION ENHANCEMENT IN TERBIUM-RUHEMANNS PURPLE COMPLEXES

被引：11

作者：

ALAOUI, IM ^{[1
]}

MENZEL, RE ^{[1
]}

机构：

[1] TEXAS TECH UNIV,CTR FORENS STUDIES,LUBBOCK,TX 79409

来源：

FORENSIC SCIENCE INTERNATIONAL | 1994年 / 66卷 / 03期

关键词：

EMISSION ENHANCEMENT; TERBIUM; RUHEMANNS PURPLE; FINGERPRINTS;

D O I：

10.1016/0379-0738(94)90345-X

中图分类号：

DF [法律]; D9 [法律]; R [医药、卫生];

学科分类号：

0301 ; 10 ;

摘要：

Luminescent lanthanide ions such as Eu3+ and Tb3+ show emission enhancement, when complexed with Ruhemann's Purples (RPs, reaction products of ninhydrin and ninhydrin analogs with amino acids) via intramolecular energy transfer from the RP ligands (good absorbers) to the ions Eu3+ and Tb+3 (efficient emitters). The authors present the optical spectroscopic features (absorption, excitation, and emission spectra) of the complexes formed with RPs and Tb. The emission lifetimes of these complexes are also addressed.

引用

页码：203 / 211

页数：9

共 13 条

[1] IMMUNOASSAYS WITH TIME-RESOLVED FLUORESCENCE SPECTROSCOPY - PRINCIPLES AND APPLICATIONS
DIAMANDIS, EP
[J]. CLINICAL BIOCHEMISTRY, 1988, 21 (03) : 139 - 150
[2] SUBSTITUENT EFFECTS ON INTRAMOLECULAR ENERGY TRANSFER .2. FLUORESCENCE SPECTRA OF EUROPIUM + TERBIUM BETA-DIKETONE CHELATES
FILIPESCU, N
SAGER, WF
SERAFIN, FA
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (11) : 3324 - &
[3] TIME-RESOLVED FLUOROMETRIC-DETERMINATION OF TERBIUM IN AQUEOUS-SOLUTION
HEMMILA, I
[J]. ANALYTICAL CHEMISTRY, 1985, 57 (08) : 1676 - 1681
[4] KAZANSKAYA NA, 1970, OPT SPECTROSC, V28, P619
[5] FLUORESCENCE OF EUROPIUM(III) TRAPPED IN SILICA-GEL GLASS AS A PROBE FOR CATION BINDING AND FOR CHANGES IN CAGE SYMMETRY DURING GEL DEHYDRATION
LEVY, D
REISFELD, R
AVNIR, D
[J]. CHEMICAL PHYSICS LETTERS, 1984, 109 (06) : 593 - 597
[6] MATHEWS JA, 1988, ANAL BIOCHEM, V169, P1
[7] MEKKAOUI AI, 1993, J FORENSIC SCI, V38, P506
[8] MEKKAOUI I, 1992, B AM PHYS SOC, V37, P1083
[9] MEKKAOUI I, 1992, THESIS TEXAS TU
[10] MENZEL ER, 1990, J FORENSIC SCI, V35, P35

← 1 2 →