KINETICS OF REACTION BETWEEN SODIUM HYDROXIDE AND BROMOPENTAMMINECOBALT (3) PERCHLORATE IN AQUEOUS SOLUTION

被引：9

作者：

DAVIES, MB

LALOR, GC

机构：

[1] Chemistry Department, University of the West Indies

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 03期

关键词：

D O I：

10.1016/0022-1902(69)80027-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Second-order rate constants for the reaction between bromopentamminecobalt (III) and hydroxide ions were measured spectrophotometrically at low ionic strengths in the temperature range 2·8-20°. The variation of rate constants with ionic strength follows the predictions of the Brönsted-Bjerrum theory. At zero ionic strength the variation of the rate constant with respect to temperature is reproduced by the equation k20 = 1·596 × 1021exp(-27,620 ± 187/RT) 1.m-1sec-1. © 1969.

引用

页码：799 / &

共 18 条

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