REACTIVITY CHARACTERISTICS OF A NEW FORM OF CHITOSAN - FACILE N-PHTHALOYLATION OF CHITOSAN PREPARED FROM SQUID BETA-CHITIN FOR EFFECTIVE SOLUBILIZATION

被引：29

作者：

KURITA, K

TOMITA, K

TADA, T

NISHIMURA, S

ISHII, S

机构：

[1] Department of Industrial Chemistry, Faculty of Engineering, Seikei University, Musashino-shi, Tokyo

来源：

POLYMER BULLETIN | 1993年 / 30卷 / 04期

关键词：

D O I：

10.1007/BF00338476

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new form of chitosan prepared by deacetylating squid beta-chitin was subjected to N-phthaloylation to evaluate the reactivity as compared with that of the conventional chitosan prepared from shrimp alpha-chitin. The reaction proceeded much more efficiently with squid chitosan than shrimp chitosan to give N-phthaloylchitosan, indicating considerable differences in higher-order structures between the two kinds of chitosans. Squid chitosan thus proved to show enhanced reactivity and be superior to shrimp chitosan as a starting material for controlled regioselective chemical modifications of chitin.

引用

页码：429 / 433

页数：5

共 6 条

[1]

AUSTIN PR, 1989, CHITIN CHITOSAN, P749

[2] REFINEMENT OF STRUCTURE OF BETA-CHITIN [J].