INFRARED RAMAN AND PROTON MAGNETIC RESONANCE SPECTRA OF DICYCLOPENTADIENYLMERCURY AND RELATED COMPOUNDS

被引：45

作者：

MASLOWSKY, E

NAKAMOTO, K

机构：

[1] Department of Chemistry, Illinois Institute of Technology, Chicago, Illinois 60616, Technology Center

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 05期

关键词：

D O I：

10.1021/ic50075a017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The infrared and Raman spectra of (C5H5)2Hg and (C5H5)HgX types of compounds (X = halogen) have been compared with those of CsHe. It has been concluded that the Hg atoms of these compounds are bonded to the C5H6 rings. In (CsHshHg, the C-Hg-C bond is linear and the antisymmetric and symmetric Hg-C stretching vibrations are assigned at 348 and 321 cm-1, respectively. However, the relative orientation of the C5H5 rings could not be determined, since there was no appreciable vibrational coupling betrveen the vibrations of the two C5H5 rings. © 1969, American Chemical Society. All rights reserved.

引用

页码：1108 / +

页数：1

共 21 条

[1] LOW-FREQUENCY INFRARED SPECTRA OF SOME COMPLEX HALIDES OF ZINC CADMIUM + MERCURY
COATES, GE
RIDLEY, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1964, (JAN): : 166 - &
[2] COTTON FA, 1966, 9 P ROB A WELCH F C, P213
[3] DVORYANT.GG, 1966, DOKL AKAD NAUK SSSR+, V166, P868
[4] UBER AROMATENKOMPLEXE VON METALLEN .27. DIPOLMOMENTE VON AROMATEN-METALL-KOMPLEXEN
FISCHER, EO
SCHREINER, S
[J]. CHEMISCHE BERICHTE-RECUEIL, 1959, 92 (04): : 938 - 948
[5] CYCLOPENTADIENYLSILANE DERIVATIVES
FRISCH, KC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (23) : 6050 - 6051
[6] RAMAN UND IR-SPEKTRUM DES CYCLOPENTADIENS
FRITZ, HP
SCHAFER, L
[J]. SPECTROCHIMICA ACTA, 1965, 21 (01): : 211 - &
[7] INFRARED AND RAMAN SPECTRAL STUDIES OF PI-COMPLEXES FORMED BETWEEN METALS AND CNHN RINGS
FRITZ, HP
[J]. ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1964, 1 : 239 - 316
[8] INFRARED AND RAMAN SPECTRA AND VIBRATIONAL ASSIGNMENT OF CYCLOPENTADIENE
GALLINELLA, E
FORTUNATO, B
MIRONE, P
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1967, 24 (03) : 345 - +
[9] VIBRATIONAL SPECTRA OF METHYL MERCURIC CHLORIDE BROMIDE IODIDE AND CYANIDE
GOGGIN, PL
WOODWARD, LA
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1966, 62 (522P): : 1423 - &
[10] VIBRATIONAL SPECTRA OF ORGANOMETALLIC COMPOUNDS .I. ALKYL AND ARYL COMPOUNDS OF MERCURY(2)
GREEN, JHS
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1968, A 24 (07): : 863 - &

← 1 2 3 →