The potential function for the CCC bending in carbon suboxide

被引：33

作者：

Clark, Allan ^{[1
]}

Seip, Hans M. ^{[2
]}

机构：

[1] Univ Manchester, Inst Sci & Technol, Dept Chem, Manchester M60 1QD, Lancs, England

[2] Univ Oslo, Dept Chem, Oslo 3, Norway

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 6卷 / 05期

关键词：

D O I：

10.1016/0009-2614(70)85190-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The CCC beading In C3O2 has been studied using results from recent spectroscopic and electron diffraction investigations of the compound. The potential V(r) = 2400 r(2) + 14000/(2.2 + r(2)) (cm(-1)), which has a small maximum of about 50 cm(-1) for alpha = 0 degrees (2 alpha = 180 degrees angle CCC) and minimum for alpha about 11 degrees, seems consistent with most of the available experimental data. However, a potential with no barrier for alpha = 0 degrees cannot be ruled out.

引用

页码：452 / 456

页数：5

共 12 条

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