PROTONATION AND REARRANGEMENT OF BIS(ACETYLIDE) COMPLEXES OF IRON - FORMATION OF COORDINATED ETA-3-BUTENYNES

被引：58

作者：

FIELD, LD

GEORGE, AV

PURCHES, GR

SLIP, IHM

机构：

[1] Department of Organic Chemistry, University of Sydney

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 09期

关键词：

D O I：

10.1021/om00045a014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(acetylide) complexes of iron(II) phosphines Fe(DMPE)2 (DMPE = (CH3)2PCH2CH2P(CH3)2) rearrange in the presence of mild acids to give cationic complexes of general formula [Fe(eta-3-C(C=CR)=CHR)(DMPE)2]+ containing an eta-3-bound but-1-en-3-yn-2-yl ligand. A number of iron complexes with coordinated butenyne ligands have been fully characterized as their hexafluorophosphate salts, and their synthesis and properties are reported.

引用

页码：3019 / 3023

页数：5

共 37 条

[1] REGIOSELECTIVE HOMOMERIZATION AND CODIMERIZATION OF 1-ALKYNES LEADING TO 2,4-DISUBSTITUTED 1-BUTEN-3-YNES BY CATALYSIS OF A (ETA-5-C5ME5)2TICL2/RMGX SYSTEM
AKITA, M
YASUDA, H
NAKAMURA, A
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1984, 57 (02) : 480 - 487
[2] REACTIONS OF MOLECULAR-HYDROGEN COMPLEXES [RUH(ETA-2-H2)P4]BF4 WITH ALKYNES - PREPARATION AND CRYSTAL-STRUCTURE OF THE [RU(ETA-3-(PARA-TOLYL)C3CH(PARA-TOLYL))(PHP(OET)2)4]BPH4 DERIVATIVE
ALBERTIN, G
AMENDOLA, P
ANTONIUTTI, S
IANELLI, S
PELIZZI, G
BORDIGNON, E
[J]. ORGANOMETALLICS, 1991, 10 (08) : 2876 - 2883
[3] POLYAZOLYL CHELATE CHEMISTRY .3. (SIGMA-ORGANYL)(TRIS(PYRAZOL-1-YL)BORATO)RUTHENIUM COMPLEXES
ALCOCK, NW
HILL, AF
MELLING, RP
[J]. ORGANOMETALLICS, 1991, 10 (11) : 3898 - 3903
[4] LIGAND-CENTERED COUPLING OF THE ALKYNYL RADICAL CATIONS [MO(C=CR)(PH2PCH2CH2PPH2)(ETA-C7H7)]+ (R=PH OR BUN) - CRYSTAL-STRUCTURE OF THE DIMERIC PRODUCT [MO2(PH2PCH2CH2PPH2)2(ETA-C7H7)2(MU-C4PH2)][PF6]2
BEDDOES, RL
BITCON, C
RICALTON, A
WHITELEY, MW
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 367 (03) : C21 - C24
[5] STABLE CATIONIC COMPLEX OF IRON CONTAINING PHENYLVINYLIDENE LIGAND
BELLERBY, JM
MAYS, MJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 117 (01) : C21 - C22
[6] REACTIONS OF THE TRIGONAL-BIPYRAMIDAL COBALT(I) HYDRIDE [(P(CH2CH2PPH2)3)COH] WITH 1-ALKYNES - SYNTHESIS AND REACTIVITY OF ACETYLIDE, ALKENYL, AND VINYLIDENE COMPLEXES
BIANCHINI, C
INNOCENTI, P
MELI, A
PERUZZINI, M
ZANOBINI, F
ZANELLO, P
[J]. ORGANOMETALLICS, 1990, 9 (09) : 2514 - 2522
[7] BRUCE MI, 1983, ADV ORGANOMET CHEM, V22, P59
[8] CONVENIENT SYNTHESIS OF 1,2-BIS(DICHLOROPHOSPHINO)ETHANE, 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE AND 1,2-BIS(DIETHYLPHOSPHINO)ETHANE
BURT, RJ
CHATT, J
HUSSAIN, W
LEIGH, GJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 182 (02) : 203 - 206
[9] CONVERSION OF A (METHOXYMETHYL)IRIDIUM(I) ACETYLENE COMPLEX TO A METALLACYCLOBUTENE IRIDIUM(III) COMPLEX - CRYSTAL AND MOLECULAR-STRUCTURES OF "IR(CH2OCH3)(P-TOL-C=C-P-TOL)(PME3)3 AND FAC-IR[CH2C(P-TOL)=C(P-TOL)]BR(PME3)3
CALABRESE, JC
ROE, DC
THORN, DL
TULIP, TH
[J]. ORGANOMETALLICS, 1984, 3 (08) : 1223 - 1230
[10] SOME HYDRIDO-COMPLEXES OF IRON(II)
CHATT, J
HAYTER, RG
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1961, (DEC): : 5507 - &

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