SYNTHESIS, STRUCTURE AND REACTIONS OF ORGANOMETALLIC COMPOUNDS OF GROUPS 1-3 CONTAINING BULKY SILICON-SUBSTITUTED ALKYL-GROUPS

被引：83

作者：

EABORN, C

IZOD, K

SMITH, JD

机构：

[1] School of Chemistry and Molecular Sciences, University of Sussex, Brighton

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 500卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

SILICON; GROUPS; 1-3; TRIS(TRIMETHYLSILYL)METHYL;

D O I：

10.1016/0022-328X(95)00528-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A review is presented of the chemistry of organometallic compounds containing very bulky ligands of the types C(SiMe(2)X)(3) (X = Me, Ph or OMe) and C(SiMe(3))(2)(SiMe(2)X) (X = Ph or OMe) attached to metals of Groups 1-3. The structures and reactions of these compounds show novel features not observed for analogues containing less bulky alkyl groups.

引用

收藏

页码：89 / 99

页数：11

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