A NEW COMPOUND - UNF

被引：12

作者：

YOSHIHARA, K

KANNO, M

MUKAIBO, T

机构：

[1] Department of Nuclear Engineering, University of Tokyo, Bunkyo-ku, Tokyo

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 04期

关键词：

D O I：

10.1016/0022-1902(69)80146-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new compound UNF has been prepared by the reaction of UF4 with silicon and nitrogen. The crystal structure of UNF has been determined to be tetragonal with dimensions of a = 5·612 ± 0·001 A ̊, b = 5·712 ± 0·001 A ̊. This compound is converted to U2N3 in nitrogen atmosphere, and also converted to UN in argon atmosphere at elevated temperatures. This compound is not stable in air even at room temperature due to its oxidation. © 1969.

引用

页码：985 / +

页数：1