EXCESS MOLAR VOLUMES OF ETHYL FORMATE OR ETHYL-ACETATE + 1-CHLOROALKANE AT 298.15 K

被引：42

作者：

ORTEGA, J ^{[1
]}

MATOS, JS ^{[1
]}

PAZANDRADE, MI ^{[1
]}

FERNANDEZ, J ^{[1
]}

机构：

[1] UNIV SANTIAGO DE COMPOSTELA,FAC FIS,DEPT FIS FUNDAMENTAL,SANTIAGO DE COMPOSTELA,SPAIN

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1987年 / 32卷 / 04期

关键词：

ESTERS - THERMODYNAMIC PROPERTIES - Measurements;

D O I：

10.1021/je00050a024

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Excess molar volumes at 298. 15 K of ethyl formate or ethyl acetate with 1-chloroalkanes (from C//5 to C//8) were calculated indirectly from densities. The V**E//m values were positive over the concentration range, increasing, for any one ester, with the length of the chain of the 1-chloroalkane and being smaller for the acetate than for ethyl formate.

引用

页码：464 / 466

页数：3

共 13 条

[1]

DESPHANDE DD, 1981, J CHEM ENG DATA, V85, P1261

[2]

DOAMNGUYEN TH, 1978, J CHEM ENG DATA, V23, P18

[3] EXCESS THERMODYNAMICS FUNCTIONS OF 1-PROPANOL + METHYL PROPANOATE AND 1-PROPANOL + METHYL BUTANOATE SYSTEMS [J].

FERNANDEZ, J ;

BERRO, C ;

ANDRADE, MIP .

FLUID PHASE EQUILIBRIA, 1985, 20 (MAR) :145-153

[4] THERMODYNAMICS OF ESTER-CONTAINING MIXTURES - EXCESS ENTHALPIES AND EXCESS VOLUMES FOR ALKYL ACETATES AND ALKYL BENZOATES + ALKANES, + BENZENE, + TOLUENE, AND + ETHYLBENZENE [J].

GROLIER, JPE ;

BALLET, D ;

VIALLARD, A .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1974, 6 (09) :895-908

[5]

KRISHNAIAH A, 1980, PHASE EQUILIB FLUID, P94

[6] GROUP CONTRIBUTION MOLECULAR MODEL OF LIQUIDS AND SOLUTIONS [J].

NITTA, T ;

TUREK, EA ;

GREENKORN, RA ;

CHAO, KC .

AICHE JOURNAL, 1977, 23 (02) :144-160

[7] EXCESS MOLAR VOLUMES OF (ETHYL FORMATE + EACH OF SEVERAL ALKANOLS) AT 298.15-K [J].

ORTEGA, J ;

BRAVO, R ;

JIMENEZ, E ;

ANDRADE, MIP .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1986, 18 (05) :403-406

[8] EXCESS MOLAR VOLUMES OF BINARY-MIXTURES OF BUTYL FORMATE WITH NORMAL ALCOHOLS AT 298.15 K [J].

ORTEGA, J .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1985, 30 (04) :465-467

[9] EXCESS MOLAR VOLUMES OF (ETHYL FORMATE OR ETHYL-ACETATE + AN ISOMER OF HEXANOL) AT 298.15-K [J].

ORTEGA, J ;

MATOS, JS ;

ANDRADE, MIP ;

JIMENEZ, E .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1985, 17 (12) :1127-1132

[10] HME AND VME OF SOME (1-CHLOROBUTANE + ALKANOL OR CYCLOHEXANOL) MIXTURES [J].

PEREZ, P ;

ROYO, F ;

GRACIA, M ;

LOSA, CG .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1985, 17 (08) :711-718

← 1 2 →