Internal excitation in non-reactive molecular collisions: Resonances in elastic scattering of atoms by diatomic molecules

被引:21
作者
Levine, R. D. [1 ]
Johnson, B. R.
Muckezman, J. T.
Bernstein, R. Bz
机构
[1] Univ Wisconsin, Inst Theoret Chem, Madison, WI 53706 USA
[2] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
关键词
D O I
10.1016/0009-2614(68)80006-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Resonances in slow molecular collisions are demonstrated by exact numerical solution of the close-coupled equations for rotational excitation, including closed channels. The breakdown of the adiabatic approximation is exhibited. Resonance energies can be essentially predicted by a "best local" approximation.
引用
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页码:517 / 520
页数:4
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