PD-CATALYZED REGIOSELECTIVE AND STEREOSELECTIVE CARBOXYLATION OF CYCLOALKANES WITH CO

被引：21

作者：

SATOH, K

WATANABE, J

TAKAKI, K

FUJIWARA, Y

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 08期

关键词：

D O I：

10.1246/cl.1991.1433

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of cycloalkanes with CO via the C-H bond activation by Pd(OAc)2 catalyst have been found to proceed regio- and stereo-selectively to give corresponding carboxylic acids. The reactivity of C-H bonds of cyclo-alkanes decreases in the order: tert- > sec- > prim-carbon, and the stereochemistry of the substituents on the main products is all equatorial.

引用

页码：1433 / 1436

页数：4