METALLACUMULENES - NEW ALLENYLIDENE-RUTHENIUM COMPLEXES - CRYSTAL-STRUCTURE OF A CATIONIC [(PH2PCH2PPH2)2(CL)RU=C=C=CR1R2]+ DERIVATIVE

被引：72

作者：

PIRIO, N ^{[1
]}

TOUCHARD, D ^{[1
]}

TOUPET, L ^{[1
]}

DIXNEUF, PH ^{[1
]}

机构：

[1] UNIV RENNES 1,PHYS CRISTALLINE LAB,CNRS,URA 804,F-35042 RENNES,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 14期

关键词：

D O I：

10.1039/c39910000980

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The activation with cis-RuCl2(Ph2PCH2PPh2)2 1 of HC = C-CR2OH and HC = C-C(Me) = CH2 leads to allenylidenes trans-(Cl)Ru+ = C = C = CR2(Ph2PCH2PPh2)2 (R = Ph, Me, p-Cl-Ph) and that of HC = C-C = C-CPh2OSiMe3 affords a new allenylidene-ruthenium complex 9 via an intramolecular ortho C-H bond addition.

引用

页码：980 / 982

页数：3

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