BIS(TETRATHIAFULVALENYL)SULPHIDE [(TTF)2S] - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE

被引：52

作者：

BRYCE, MR ^{[1
]}

COOKE, G ^{[1
]}

DHINDSA, AS ^{[1
]}

ANDO, DJ ^{[1
]}

HURSTHOUSE, MB ^{[1
]}

机构：

[1] QUEEN MARY & WESTFIELD COLL,DEPT CHEM,LONDON E1 4NS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 13期

关键词：

D O I：

10.1016/S0040-4039(00)91732-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bis(tetrathiafulvalenyl)sulphide [(TTF)2S] has been synthesised by reaction of monolithiated TTF with di(phenylsulphonyl)sulphide, and characterised by cyclic voltammetry and single crystal X-ray analysis, which reveals a remarkably close two-dimensional chalcogen network in the solid state. The synthesis of (TTF)2Se, using the selenating reagent di(phenylsulphonyl)diselenide, is also reported.

引用

页码：1783 / 1786

页数：4

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