RHODIUM COMPLEXES CONTAINING SUBSTITUTED HYDRAZINES

被引：17

作者：

DAVIES, CJ ^{[1
]}

DODD, IM ^{[1
]}

HARDING, MM ^{[1
]}

HEATON, BT ^{[1
]}

JACOB, C ^{[1
]}

RATNAM, J ^{[1
]}

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 3BX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 06期

关键词：

D O I：

10.1039/dt9940000787

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of trans-[Rh(CO)(PPh3)(OClO3)] has been determined, an it has been established that the perchlorate group is easily displaced by substituted hydrazines to give trans-[Rh(CO)(PPh3)2L]ClO4 (L = NH2NH2-xRx; x = 1 or 2; R = Me or Ph). X- Ray crystallography shows that for all these complexes the unsymmetrically substituted hydrazine co-ordinates to rhodium via the NH2 group.

引用

收藏

页码：787 / 792

页数：6

相关论文

共 37 条

[1] STRUCTURAL STUDIES OF SUBSTITUTED HYDRAZINE COMPLEXES .2. CRYSTAL AND MOLECULAR-STRUCTURE OF (ETA-CYCLO-OCTA-1,5-DIENE)TRIS(NN-DIMETHYLHYDRAZINE)HYDRIDORUTHENIUM(II) HEXAFLUOROPHOSPHATE [J].

ASHWORTH, TV ;

NOLTE, MJ ;

SINGLETON, E .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (09) :1040-1042

[2] CATIONIC RUTHENIUM(II) SYSTEMS .1. PREPARATION AND REACTIVITY OF DIENE(HYDRAZINE)RUTHENIUM(II) CATIONS, AND FORMATION OF AMINO-BONDED HYDRAZONE COMPLEXES [J].

ASHWORTH, TV ;

SINGLETON, E ;

HOUGH, JJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (19) :1809-1815

[3] 5-COORDINATE HYDRIDO-CARBONYL COMPLEXES OF RHODIUM AND IRIDIUM AND THEIR ANALOGY WITH COH(CO)4 [J].

BATH, SS ;

VASKA, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (21) :3500-&

[4]

BEURSKENS PT, 1984, 19841 CRYST LAB TECH

[5]

Bottomley F., 1970, QUART REV CHEM SOC, V24, P617

[6]

BROOMHEAD JA, 1977, ADV CHEM SER, V162, P421

[7]

CALABRESE JC, 1972, THESIS U WISCONSIN M

[8] SYNTHESIS AND X-RAY CRYSTALLOGRAPHIC CHARACTERIZATION OF NEW DINUCLEAR BIS(PHENYLDIAZENIDO)MOLYBDENUM COMPLEXES [(MO(C6H5N2)2CL(MU-OR)(C6H5NHNH2))2] [(MO(C6H5N2)2OR(MU-OR)(C6H5NHNH2))], [(MO(C6H5N2)2(MU-OR)(C6H5CONHO))2] AND [(MO(C6H5N2)2CL(MU-OET)(ETOH))2] [J].

CHILOU, V ;

GOUZERH, P ;

JEANNIN, Y ;

OLIVARES, G ;

ROBERT, F ;

HSIEH, TC ;

ZUBIETA, J .

POLYHEDRON, 1989, 8 (01) :29-38

[9] INFLUENCE OF HYDRATION ON BASE STRENGTH .3. ALKYLHYDRAZINES [J].

CONDON, FE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (20) :4491-&

[10] CRYSTAL STRUCTURE OF COPPER(I) CYANIDE HYDRAZINE COMPLEX CUCN.N2H4 [J].

CROMER, DT ;

LARSON, AC ;

ROOF, RB .

ACTA CRYSTALLOGRAPHICA, 1966, 20 :279-&

← 1 2 3 4 →