FACILE SYNTHESIS OF HIGHLY SUBSTITUTED PD-ETA(3)-ALLYL COMPLEXES CONTAINING NITROGEN LIGANDS

被引：54

作者：

RULKE, RE

KLIPHUIS, D

ELSEVIER, CJ

FRAANJE, J

GOUBITZ, K

VANLEEUWEN, PWNM

VRIEZE, K

机构：

[1] JH VANT HOFF RES INST,ANORGAN CHEM LAB,1018 WV AMSTERDAM,NETHERLANDS

[2] UNIV AMSTERDAM,DEPT CRYSTALLOG,1018 WV AMSTERDAM,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 15期

关键词：

D O I：

10.1039/c39940001817

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first examples of quantitative migratory insertion of allene, 1,1-dimethylallene (DMA) and tetramethylallene (TMA) into alkyl and acyl palladium complexes containing bidentate and terdentate nitrogen ligands are presented; very stable palladium eta(3)-allyl compounds containing 2,2'-bipyridine and 2-(2-{[(6'-methyl-2-pyridyl)methylene]amino}ethyl)-pyridine and an exceptional eta(1)-allyl palladium complex containing terpy have been obtained.

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页码：1817 / 1819

页数：3

相关论文

共 29 条

[1]

BOSNICH B, 1982, PURE APPL CHEM, V54, P482

[2] SYNTHETIC METHODOLOGY INVOLVING THE CARBOPALLADATION OF ALLENES [J].

CAZES, B .

PURE AND APPLIED CHEMISTRY, 1990, 62 (10) :1867-1878

[3] SOME REACTIONS OF ALLENE AND ACETYLENES WITH VINYL-PLATINUM AND METHYL-PALLADIUM COMPLEXES [J].

CLARK, HC ;

MILNE, CRC ;

WONG, CS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 136 (02) :265-279

[4] X-RAY SCATTERING FACTORS COMPUTED FROM NUMERICAL HARTREE-FOCK WAVE FUNCTIONS [J].

CROMER, DT ;

MANN, JB .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :321-&

[5] INFLUENCE OF LIGANDS AND ANIONS ON THE INSERTION OF ALKENES INTO PALLADIUM ACYL AND PALLADIUM CARBOMETHOXY BONDS IN THE NEUTRAL COMPLEX (DPPP)PD(C(O)CH3)CL AND THE IONIC COMPLEXES [(P-P)PDR(L)]+SO3CF3- (P-P = DPPE, DPPP, DPPB, R = C(O)CH3, L = CH3CN, PPH3, R = C(O)OCH3, L = PPH3) [J].

DEKKER, GPCM ;

ELSEVIER, CJ ;

VRIEZE, K ;

VANLEEUWEN, PWNM ;

ROOBEEK, CF .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 430 (03) :357-372

[6] EFFICIENT PALLADIUM CATALYSTS FOR THE COPOLYMERIZATION OF CARBON-MONOXIDE WITH OLEFINS TO PRODUCE PERFECTLY ALTERNATING POLYKETONES [J].

DRENT, E ;

VANBROEKHOVEN, JAM ;

DOYLE, MJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 417 (1-2) :235-251

[7]

Drent E., 1984, [No title captured], Patent No. 121965

[8]

Hall S. R., 1992, XTAL 3 2 REFERENCE M

[9] REACTION OF (PI-ALLYL)PALLADIUM COMPLEXES FROM ALLENE WITH NUCLEOPHILES - SYNTHESIS OF CONJUGATED EXOCYCLIC DIENES [J].

HEGEDUS, LS ;

KAMBE, N ;

TAMURA, R ;

WOODGATE, PD .

ORGANOMETALLICS, 1983, 2 (11) :1658-1661

[10]

LARSON AC, 1969, INCLUSION SECONDARY