EFFECTS OF METALLIC AND D2EHPA IMPURITIES ON NICKEL ELECTROWINNING FROM AQUEOUS SULFATE BATHS

被引:22
作者
KUZECI, E [1 ]
KAMMEL, R [1 ]
GOGIA, SK [1 ]
机构
[1] REG RES LAB,BHUBANESWAR 751013,ORISSA,INDIA
关键词
D O I
10.1007/BF00578087
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The presence of metallic and organic solvent impurities in pregnant electrolyte during hydrometallurgical processing causes problems in nickel electrowinning. To overcome these problems, a study on the combined effects of metallic and D2EHPA impurities, on nickel electrodeposition has been carried out. The effects of such impurities on deposit physical appearance, current efficiency, deposit contamination, crystallographic orientation and deposit morphology are discussed. Based on the experimental data and observations, it is possible to achieve smooth and perfect nickel sheet with reasonable current efficiency and purity from the contaminated leach liquors of nickel bearing raw materials being processed in the Regional Research Laboratory, Bhubaneswar. Moreover, the economy of the nickel electrowinning process can be improved by careful selection of experimental conditions.
引用
收藏
页码:730 / 736
页数:7
相关论文
共 27 条
[1]   EFFECTS OF CHLORIDE ON THE ORIENTATION OF NICKEL DEPOSITS [J].
BANERJEE, BC ;
GOSWAMI, A .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1959, 106 (07) :590-592
[2]  
BOLDT JR, 1967, WINNING NICKEL ITS G, P336
[3]  
Dennis J. K., 1968, Transactions of the Institute of Metal Finishing, V46, P185
[4]  
DIGGIN MB, 1946, MONTHLY REV AM ELECT, V33, P524
[5]  
DIGGIN MB, 1946, MONTHLY REV AM ELECT, V33, P513
[6]  
EVALNNIKOV LM, 1939, LENINGRAD IND I, P3
[7]  
EWING DT, 1952, PLATING, V39, P1343
[8]   THE EFFECT OF MAGNESIUM SALTS ON NICKEL PLATING BATHS [J].
GENEIDY, A ;
KOEHLER, WA ;
MACHU, W .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1959, 106 (05) :394-403
[9]   THE EFFECT OF CO2+, CU2+, FE2+ AND FE3+ DURING ELECTROWINNING OF NICKEL [J].
GOGIA, SK ;
DAS, SC .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1991, 21 (01) :64-72
[10]   THE EFFECTS OF MG-2+, MN-2+, ZN-2+, AND AL-3+ ON THE NICKEL DEPOSIT DURING ELECTROWINNING FROM SULFATE BATH [J].
GOGIA, SK ;
DAS, SC .
METALLURGICAL TRANSACTIONS B-PROCESS METALLURGY, 1988, 19 (06) :823-830