SYNTHESIS AND REVERSIBLE STEREOMUTATION OF OPTICALLY-ACTIVE POLY((S)-DIPHENYL(1-METHYLPYRROLIDIN-2-YL)METHYL METHACRYLATE)

被引：61

作者：

OKAMOTO, Y ^{[1
]}

NAKANO, T ^{[1
]}

ONO, E ^{[1
]}

HATADA, K ^{[1
]}

机构：

[1] OSAKA UNIV, FAC ENGN SCI, DEPT CHEM, TOYONAKA, OSAKA 560, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 03期

关键词：

D O I：

10.1246/cl.1991.525

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Anionic polymerization of (+)-(S)-diphenyl(1-methyl-pyrrolidin-2-yl)methyl methacrylate gave an optically active polymer of helical conformation of single screwsense. The polymer exhibited a reversible helix-helix transition in a solution of methanol containing an acid.

引用

页码：525 / 528

页数：4

共 19 条

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