STRUCTURE OF [RHH2(PPH3)2(BIPY)]CL (BIPY = 2,2'-BIPYRIDYL) FROM MULTINUCLEAR NMR-STUDIES

被引：10

作者：

HEATON, BT ^{[1
]}

JACOB, C ^{[1
]}

HEGGIE, W ^{[1
]}

PAGE, PR ^{[1
]}

VILLAX, I ^{[1
]}

机构：

[1] HOVIONE SOCIEDA QUIM LDA,RES LABS,P-2670 LOURES,PORTUGAL

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1991年 / 29卷

关键词：

RHODIUM COMPLEXES INEPT N-15 NMR; RH-103; NMR; H-1; P-31; 2,2'-BIPYRIDYL;

D O I：

10.1002/mrc.1260291307

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By the use of the INEPT pulse sequence it has been possible to obtain N-15 and Rh-103 NMR data on [RhH2(PPh3)2(bipy)]Cl (bipy = 2,2'-bipyridyl) containing natural abundance N-15 and prove the stereochemistry; H-1 and P-31 NMR data are also reported for [RhH2(PPh3)2(bipy)]Cl which can be easily prepared in the pure state by the reaction of [RhCl(PPh3)3] or [Rh2Cl2(PPh3)4] with bipy ([Rh]: [bipy] = 1:1) under an H-2 atmosphere.

引用

页码：S21 / S24

页数：4

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