TRANSINFLUENCE OF A COORDINATING NITROSYL GROUP - PREPARATION AND STRUCTURE OF CIS-TRIHALOGENO(8-QUINOLINOLATO OR ITS DERIVATIVE)NITROSYLRUTHENATE(1-)

被引：16

作者：

MIKI, E ^{[1
]}

HARADA, K ^{[1
]}

KAMATA, Y ^{[1
]}

UMEHARA, M ^{[1
]}

MIZUMACHI, K ^{[1
]}

ISHIMORI, T ^{[1
]}

NAKAHARA, M ^{[1
]}

TANAKA, M ^{[1
]}

NAGAI, T ^{[1
]}

机构：

[1] NIPPON MED COLL,CHEM LAB,NAKAHARA KU,KAWASAKI 211,JAPAN

来源：

POLYHEDRON | 1991年 / 10卷 / 06期

关键词：

D O I：

10.1016/S0277-5387(00)83616-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrous nitrosylruthenium(III) halide reacts with 8-quinolinol or its derivative (2-methyl- or 5-chloro-8-quinolinol) in ethyl alcohol or acetonitrile to give [RuX3(NO)(NO)]- [X = Cl or Br; H(N-O) = 8-quinolinol or its derivative]. All the halide ions are coordinated cis to the nitrosyl and the 8-quinolinolato oxygen trans to the nitrosyl, as found from an X-ray crystallographic study. The structure of the complex anion reflects a strong pi-acceptor ability of the nitrosyl. The compounds obtained were also examined by C-13 NMR and negative-SIMS (secondary-ion mass spectrometry).

引用

页码：583 / 589

页数：7

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