DEVELOPMENT OF CHIRAL STATIONARY PHASES CONSISTING OF POLYSACCHARIDE DERIVATIVES

被引：94

作者：

OGUNI, K ^{[1
]}

ODA, H ^{[1
]}

ICHIDA, A ^{[1
]}

机构：

[1] DAICEL CHEM IND LTD,RES CTR,ABOSHI KU,HIMEJI,HYOGO 67112,JAPAN

来源：

JOURNAL OF CHROMATOGRAPHY A | 1995年 / 694卷 / 01期

关键词：

D O I：

10.1016/0021-9673(94)00789-C

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Various chiral stationary phases (CSPs) consisting of polysaccharide derivatives were developed by adsorbing them on silica gel on the basis of information obtained from cellulose triacetate. The chiral recognition ability increases with an increase in conformational regularity. The regularity of cellulose triacetate depends greatly on the kind of solvents used in the coating procedure. This finding seems to be applicable to other coating-type CSPs based on polysaccharide derivatives. Some interactions were considered between a CSP and an enantiomer for chiral discrimination. By using C-13 NMR spectroscopy, 1-phenylethyl alcohol was chirally recognized on cellulose tris(4-methylbenzoate).

引用

页码：91 / 100

页数：10

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