STUDIES IN BASE-CATALYZED ALLENIC OXY-COPE REARRANGEMENT - AN EXPEDIENT SYNTHESIS OF FUNCTIONALIZED BICYCLO[4.3.0] AND BICYCLO[4.4.0] SYSTEMS AND 3,5-CYCLOUNDECADIEN-1-ONE

被引：22

作者：

BALAKUMAR, A ^{[1
]}

JANARDHANAM, S ^{[1
]}

RAJAGOPALAN, K ^{[1
]}

机构：

[1] UNIV MADRAS,DEPT ORGAN CHEM,GUINDY CAMPUS,MADRAS 600025,TAMIL NADU,INDIA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 20期

关键词：

D O I：

10.1021/jo00072a035

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The base-catalyzed oxy-Cope rearrangement of systems incorporating an allenic pi system was studied. The rearrangement incidentally leads to functionalized bicyclo[4.3.0]nonane 15, bicyclo[4.4.0]decanes 6 and 10, and 3,5-cycloundecadien-1-one 20. The effect of ring size and nature of the base on the rearrangement was also studied.

引用

页码：5482 / 5486

页数：5

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