POPULATIONS OF THE EXCITED-STATES AND THE RADICAL TRANSIENTS PRODUCED IN THE ELECTRON-TRANSFER REACTIONS IN LIQUID SOLUTIONS

被引：7

作者：

NAJBAR, J

TUREK, AM

机构：

[1] Faculty of Chemistry, Jagiellonian University, 30-060 Kraków

来源：

CHEMICAL PHYSICS | 1990年 / 142卷 / 01期

关键词：

D O I：

10.1016/0301-0104(90)89066-Y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The response functions of the decay of the excited singlet state of the donor (acceptor) in the presence of the acceptor (donor) and the population of the radical pairs formed due to the electron transfer in liquid solutions are derived. The velocity averaged response functions were obtained assuming that the molecular transport in a liquid system can be described in terms of the stochastic linear Langevin equations. The results derived are valid in the slow diffusion limit. Model calculations for the time evolution of the radical transients in rigid and liquid solutions are presented. © 1990.

引用

页码：35 / 45

页数：11

共 30 条

[1] DECAY-RATES OF LUMINESCENCE IN LIQUIDS [J].