NUCLEOPHILIC DISPLACEMENT CATALYZED BY TRANSITION-METAL .9. [PD2(DBA)3].CHCL3-DPPF CATALYZED CYANATION OF ARYL HALIDES AND ARYL TRIFLATES

被引：77

作者：

TAKAGI, K ^{[1
]}

SASAKI, K ^{[1
]}

SAKAKIBARA, Y ^{[1
]}

机构：

[1] KYOTO UNIV, DEPT POLYMER SCI & ENGN, KYOTO 606, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 04期

关键词：

D O I：

10.1246/bcsj.64.1118

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A catalyst system comprising [Pd2(dba)3].CHCl3 and DPPF was proved to be efficient for the cyanation of aryl iodides and aryl triflates with KCN. The reactivities of aryl substrates decreased in the order ArI>ArOTf>ArBr.

引用

页码：1118 / 1121

页数：4

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