ALTERNATIVE DESCRIPTION OF PROCESS KINETICS

被引:62
作者
VYAZOVKIN, S
机构
[1] Institute for Physico-Chemical Problems, Byelorussian University, Minsk
关键词
D O I
10.1016/0040-6031(92)87018-6
中图分类号
O414.1 [热力学];
学科分类号
摘要
The paper provides comparison between the traditional and alternative descriptions of process kinetics. Since the traditional kinetic triplet E, A, f(w) is ambiguous and suitable for simple processes only, it can describe no real kinetics. It is shown that, on the basis of isoconversional methods, the complete kinetic description can be built in the coordinates E, w, T. Because such a description is unambiguous and suitable for both simple and complex processes, it is accepted as an alternative to the traditional approach. Algorithms to transform the alternative description into the traditional form are suggested.
引用
收藏
页码:181 / 187
页数:7
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