TRANSITION-METAL COMPLEXES WITH SULFUR LIGANDS .101. SYNTHESIS AND STRUCTURE OF N2H5[FE(N2H4)(S2C6H4)(2)]CENTER-DOT-1,33N(2)H(4)

被引：17

作者：

SELLMANN, D

FRIEDRICH, H

KNOCH, F

机构：

[1] Institut für Anorganische Chemie II der Universität Erlangen-Nürnberg, Egerlandstraße 1

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1994年 / 49卷 / 05期

关键词：

IRON SULFUR HYDRAZINE COMPLEXES; SYNTHESIS; X-RAY;

D O I：

10.1515/znb-1994-0516

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Attempts to coordinate N2H4 to [Fe(S2C6H4)(2)] fragments lead to N2H5[Fe(N2H4)(S2C6H4)(2)], which crystallizes from MeOH/N2H4 solutions as the solvate [(N2H5){Fe(N2H4)(S2C6H4)(2)}.1,33 N2H4], 1, and has been characterized by X-ray structure analysis. 1 contains three discrete N2H5+ cations, four N2H4 solvate molecules and three independent [Fe(N2H4)(S2C6H4)(2)](-) anions which are connected via an extended network of N-H ... N and N-H ... S bridges. N2H5[Fe(N2H4)(S2C6H4)(2)] and 1 contain high-spin Fe(III) centers and labile N2H4 ligands.

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页码：660 / 664

页数：5

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