N1,N7-EXPEDITIOUS DIALKYLATION OF CYCLEN (1,4,7,10-TETRAAZACYCLODODECANE) - AN ASTONISHING REACTIVITY OF CYCLEN TRICARBONYL MOLYBDENUM AND CHROMIUM COMPLEXES

被引：17

作者：

PATINEC, V ^{[1
]}

YAOUANC, JJ ^{[1
]}

HANDEL, H ^{[1
]}

CLEMENT, JC ^{[1
]}

DESABBAYES, H ^{[1
]}

机构：

[1] FAC SCI & TECH BREST,CNRS,URA 322,6 AVE GORGEU,BP 809,F-29285 BREST,FRANCE

来源：

INORGANICA CHIMICA ACTA | 1994年 / 220卷 / 1-2期

关键词：

MOLYBDENUM COMPLEXES; CHROMIUM COMPLEXES; CARBONYL COMPLEXES; TETRAAZAMACROCYCLE COMPLEXES;

D O I：

10.1016/0020-1693(94)03865-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

After reaction with alkyl iodides and subsequent oxidative removal of the M(CO)3 triprotection, molybdenum and chromium fac-LM(CO)3 complexes of cyclen (L) unexpectedly lead to N1,N7-dialkylated cyclen derivatives.

引用

页码：347 / 348

页数：2

共 7 条

[1] HIGHLY REGIOSELECTIVE SYNTHESIS OF 1,7-DIPROTECTED 1,4,7,10-TETRAAZACYCLODODECANE DERIVATIVES [J].

ANELLI, PL ;

MURRU, M ;

UGGERI, F ;

VIRTUANI, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (18) :1317-1318

[2] THERMODYNAMIC, KINETIC, AND STRUCTURAL STUDY OF THE LIGATIONAL PROPERTIES OF THE MACROBICYCLIC AZA-LIGAND 4,7,10,17,23-PENTAMETHYL-1,4,7,10,13,17,23-HEPTAAZABICYCLO[11.7.5]PENTACOSANE (L1) AND OF ITS MACROCYCLIC PRECURSOR 1,4,7,13-TETRAMETHYL-1,4,7,10,13,16-HEXAAZACYCLOOCTADECANE (L2) - CRYSTAL-STRUCTURE OF [ZN(L1)(H2O)](BPH4)2 [J].

BENCINI, A ;

BIANCHI, A ;

DAPPORTO, P ;

FUSI, V ;

GARCIAESPANA, E ;

MICHELONI, M ;

PAOLETTI, P ;

PAOLI, P ;

RODRIGUEZ, A ;

VALTANCOLI, B .

INORGANIC CHEMISTRY, 1993, 32 (12) :2753-2760

[3] SYNTHESIS AND CHARACTERIZATION OF 1,7-DIMETHYL-1,4,7,10-TETRA-AZACYCLODODECANE - CRYSTAL-STRUCTURE OF THE NICKEL(II) BROMIDE MONOHYDRATE COMPLEX OF THIS MACROCYCLE - THERMODYNAMIC STUDIES OF PROTONATION AND METAL-COMPLEX FORMATION [J].

CIAMPOLINI, M ;

MICHELONI, M ;

NARDI, N ;

PAOLETTI, P ;

DAPPORTO, P ;

ZANOBINI, F .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1357-1362

[4]

LEBRIS N, 1993, TETRAHEDRON LETT, V34, P5429

[5]

PATINEC V, IN PRESS

[6] OMEGA-MONO N-ALKYLATION OF LINEAR TETRAAMINES THROUGH THE REACTION OF ALDEHYDES AND KETONES ON THEIR TRICARBONYL CHROMIUM, MOLYBDENUM OR TUNGSTEN COMPLEXES [J].

YAOUANC, JJ ;

LEBRIS, N ;

CLEMENT, JC ;

HANDEL, H ;

DESABBAYES, H .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (08) :696-698

[7] MONO N-FUNCTIONALIZATION OF CYCLIC AND LINEAR TETRAAMINES VIA THEIR TRIDENTATE TRICARBONYLCHROMIUM COMPLEXES [J].

YAOUANC, JJ ;

LEBRIS, N ;

LEGALL, G ;

CLEMENT, JC ;

HANDEL, H ;

ABBAYES, HD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (04) :206-207

← 1 →