ENANTIOSELECTIVE EPOXIDATION OF CONJUGATED DIENES AND ENYNES - TRANS-EPOXIDES FROM CIS-OLEFINS

被引：133

作者：

LEE, NH ^{[1
]}

JACOBSEN, EN ^{[1
]}

机构：

[1] UNIV ILLINOIS,DEPT CHEM,ROGER ADAMS LAB,URBANA,IL 61801

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 45期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0040-4039(91)80212-O

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric epoxidation of conjugated dienes and enynes catalyzed by (salen)Mn(III) complex 1 takes place with high chemoselectivity to afford monoepoxides exclusively. Reactions of cis-enynes proceed with very high levels of asymmetric induction, with trans-alkynyl epoxides as the major products.

引用

页码：6533 / 6536

页数：4

共 21 条

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