THE HIGHER FULLERENES - A CANDIDATE FOR THE STRUCTURE OF C78

被引：124

作者：

FOWLER, PW ^{[1
]}

BATTEN, RC ^{[1
]}

MANOLOPOULOS, DE ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1991年 / 87卷 / 18期

关键词：

D O I：

10.1039/ft9918703103

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A systematic search reveals five C78 fullerene cages with isolated pentagons, but only one with a closed electronic shell, as predicted by Fowler's leapfrog rule. The closed-shell isomer has D3h symmetry and is the most likely candiate for the structure of C78. Like C70, it corresponds to an expansion of the C60 structure by insertion of an equatorial belt of hexagons.

引用

页码：3103 / 3104

页数：2

共 14 条

[1] BENAMOTZ D, 1991, IN PRESS J AM CHEM S
[2] THE HIGHER FULLERENES - ISOLATION AND CHARACTERIZATION OF C76, C84, C90, C94, AND C70O, AN OXIDE OF D5H-C70
DIEDERICH, F
ETTL, R
RUBIN, Y
WHETTEN, RL
BECK, R
ALVAREZ, M
ANZ, S
SENSHARMA, D
WUDL, F
KHEMANI, KC
KOCH, A
[J]. SCIENCE, 1991, 252 (5005) : 548 - 551
[3] PI-SYSTEMS IN 3 DIMENSIONS
FOWLER, PW
WOOLRICH, J
[J]. CHEMICAL PHYSICS LETTERS, 1986, 127 (01) : 78 - 83
[4] 3 CANDIDATES FOR THE STRUCTURE OF C-84
FOWLER, PW
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (12): : 1945 - 1946
[5] THE LEAPFROG PRINCIPLE - A RULE FOR ELECTRON COUNTS OF CARBON CLUSTERS
FOWLER, PW
STEER, JI
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (18) : 1403 - 1405
[6] SYSTEMATICS OF BONDING IN NON-ICOSAHEDRAL CARBON CLUSTERS
FOWLER, PW
CREMONA, JE
STEER, JI
[J]. THEORETICA CHIMICA ACTA, 1988, 73 (01): : 1 - 26
[7] CARBON CYLINDERS - A CLASS OF CLOSED-SHELL CLUSTERS
FOWLER, PW
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (12): : 2073 - 2077
[8] HOW UNUSUAL IS C-60 - MAGIC NUMBERS FOR CARBON CLUSTERS
FOWLER, PW
[J]. CHEMICAL PHYSICS LETTERS, 1986, 131 (06) : 444 - 450
[9] HAUFLER RE, 1991, IN PRESS MATER RES S
[10] THE STABILITY OF THE FULLERENES C-24, C-28, C-32, C-36, C-50, C-60 AND C-70
KROTO, HW
[J]. NATURE, 1987, 329 (6139) : 529 - 531

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