MAXIMIZATION OF THE CHEMILUMINESCENCE EFFICIENCY OF 1,4,5-TRIARYLHYDROPEROXY-4H-ISOIMIDAZOLES

被引：22

作者：

KIMURA, M ^{[1
]}

NISHIKAWA, H ^{[1
]}

KURA, H ^{[1
]}

LIM, H ^{[1
]}

WHITE, EH ^{[1
]}

机构：

[1] JOHNS HOPKINS UNIV, FAC SCI, DEPT CHEM, BALTIMORE, MD 21218 USA

来源：

CHEMISTRY LETTERS | 1993年 / 03期

关键词：

D O I：

10.1246/cl.1993.505

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A bell shape correlation curve has been found for a plot of the Hammett sigma constant and the quantum yields of the formation of excited amidines from the chemiluminescent reaction of 2-(p-dimethylaminophenyl)-4,5-di(p-X--phenyl)-4-hydroperoxy-4H-isoimidazoles (X= OCH3, H, F, Cl, CF3, and CN) with bases.

引用

页码：505 / 508

页数：4

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