PHOTOCHEMISTRY OF DITHIOCARBAMATE COMPLEXES OF NI(IV) .1. PROCESSES OF PHOTOREDUCTION OF COMPLEXES

被引：9

作者：

PLYUSNIN, VF

GRIVIN, VP

BAZHIN, NM

KUZNETZOVA, EP

LARIONOV, SV

机构：

[1] NOVOSIBIRSK STATE UNIV,NOVOSIBIRSK 630090,RUSSIA

[2] NOVOSIBIRSK INORGAN CHEM INST,NOVOSIBIRSK 630090,RUSSIA

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1993年 / 74卷 / 2-3期

关键词：

D O I：

10.1016/1010-6030(93)80107-K

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Laser flash photolysis and stationary photolysis of liquid solutions and frozen methanol matrices were used to demonstrate that the photochemical transformations of dithiocarbamate complexes of Ni(IV) occur within the coordination sphere. The spectral and kinetic characteristics of the intermediates were established; the kinetic parameters were determined for the primary process of Ni-S bond cleavage and further stages.

引用

页码：121 / 127

页数：7

共 28 条

[1]

AVDEEF A, 1970, J AM CHEM SOC, V92, P6972

[2]

BABAEVA AV, 1962, ZH NEORG KHIM+, V7, P15

[3] Preparation, Structure, and Properties of Bis(N,N-di-n-butyldithiocarbamato)gold(III) Bromide and Bis(N,N-di-n-butyldithiocarbamato)gold(III) Tetrabromoaurate(III) [J].